Whatever i know: 2013

The list for agrochemicals to be used in grape farms is out.
As compared to last year around 2 chemical compunds have been added to the list making the list to 177.
Chemicals with CIB & RC label claim for Grapes though remaining same as last year. Along with PHI special instructions for some compounds has been mentioned about spray schedule Do's and Dont's.

Wishing you a great harvest ahead.

Annexure-5

Revision date: 11th October, 2013

List of chemicals with CIB&RC label claim for use in grapes

Sr. No.	Chemical recommended for major disease & pest	Nature of chemical	Dose on formulation basis	EU MRL (mg/kg)	Pre-harvest Interval (PHI in days)
I	Downy Mildew
1.	Mancozeb 75 WP	NS	1.5-2.0 g/L	5.0	35 (avoid using after fruit set)
2.	Propineb 70 WP	NS	3.0 g/L	1.0	40 (avoid using after fruit set)
3.	COC 50 WP	NS	2.5 g/L, 2.4 g/L	50.0	42 (avoid using after fruit set)
4.	Chlorothalonil 75 WP	NS	2.0 g/L	3.0	60
5.	Fosetyl Al 80 WP	S	1.4-2.0 g/L	100.0	7
6.	Metalaxyl + Mancozeb 8+64 WP	S+NS	2.5 g/L	2.0 + 5.0	66
6a.	Metalaxyl-M + Mancozeb 4+64 WP	S+NS	2.5 g/L	2.0 + 5.0	66
7.	Cymoxanil + Mancozeb 8+64 WP	S+NS	2.0 g/L	0.2 + 5.0	66
8.	Dimethomorph 50 WP + Mancozeb 75WP as tank mixture	S+NS	0.5 to 0.75 g/L + 2.0 g/L	3.0 + 5.0	66
9.	Fenamidone + Mancozeb 10+50 WG	S+NS	2.5 to 3 g/L	0.5 + 5.0	66
10.	Azoxystrobin 23 SC	S	494 mL/ha	2.0	7
11.	Iprovalicarb + Propineb 5.5+61.25WP	S+NS	2.25 g/L	2.0 + 1.0	55

Sr. No.	Chemical recommended for major disease & pest	Nature of chemical	Dose on formulation basis	EU MRL (mg/kg)	Pre-harvest Interval (PHI in days)
12.	Famoxadone 16.6 % + Cymoxanil 22.1 % SC	S+NS	500 mL/ha	2.0 + 0.2	27
13.	Kresoxim methyl 44.3 SC	S	600-700 mL/ha	1.0	30
14.	Fenamidone 4.44% + Fosetyl-Al 66.66% WDG	S	2 to 2.5 kg/ha	0.5 + 100	27
15.	Pyraclostrobin 5% + Metiram 55% 60WG	S+NS	1.5-1.75 kg/ha	1+5	15
16.	Mandipropamid 23.4% SC	NS	0.8 mL/L	2.0	5
II	Powdery Mildew
17.	Penconazole 10 EC	S	0.50 mL/L	0.2	50
18.	Triadimefon 25 WP	S	0.50-1.0 g/L	2.0	45
19.	Hexaconazole 5EC	S	1.0 mL/L	0.01	60
20.	Myclobutanil 10 WP	S	0.40 g/L	1.0	30
21.	Flusilazole 40 EC	S	25 mL / 200 L	0.05	50
22.	Fenarimol 10 EC	S	0.40 mL / L	0.3	30
23.	Difenoconazole 25EC	S	0.50 mL / L	0.5	45
10a.	Azoxystrobin 23 SC	S	494 mL / ha	2.0	7
13a.	Kresoxim methyl 44.3 SC	S	600-700 mL/ha	1.0	30
24.	Dinocap 48 EC	NS	0.30 - 0.35 mL/L	0.05	50 (avoid application when tender shoots are present in canopy)
25.	Sulfur 40 SC, 55.16 SC, 80 WP, 80 WDG, 85 WP	NS	3.0 mL, 3.0 mL, 2.50 g, 1.87-2.50 g, 1.50-2.0 g/L, respectively	50.0	15
26.	Tetraconazole 3.8EW	S	0.75 mL/L	0.5	30
III	Anthracnose
2a	Propineb 70 WP	NS	3.0 g/L	1.0	40
3a.	COC 50 WP	NS	2.5 g/L, 2.40 g/L	50.0	42 (avoid using after fruit set)
27.	Carbendazim 50 WP, 46.27 SC	S	1.0 g/L, 1.0 mL/L	0.30	50

Sr. No.	Chemical recommended for major disease & pest	Nature of chemical	Dose on formulation basis	EU MRL (mg/kg)	Pre-harvest Interval (PHI in days)
IV	Flea beetles
28.	Imidacloprid 17.8 SL	S	0.30 mL/L	1.0	60 (Use of imidacloprid should be avoided before and during flowering stage)
29.	Lambda-cyhalothrin 05 CS	NS	0.50 mL/L	0.2	30
V	Thrips
30.	Emamectin benzoate 05 SG	NS	0.22 g/L	0.05	25
31.	Fipronil 80 WG	NS	0.05 g/L	0.005	60 (only one application before flowering stage)
28a.	Imidacloprid 17.8 SL	S	0.30 mL/L	1.0	60 (Use of imidacloprid should be avoided before and during flowering stage)
29a.	Lambda-cyhalothrin 05 CS	NS	0.50 mL/L	0.2	30
VI	Jassids
28b.	Imidacloprid 17.8 SL	S	0.30 mL/L	1.0	60 (Use of imidacloprid should be avoided before and during flowering stage)
29b.	Lambda-cyhalothrin 05 CS	NS	0.50 mL/L	0.2	30
31a.	Fipronil 80 WG	NS	0.05 g/L	0.005	60 (only one application before flowering stage)
VII	Mealy bugs
32.	Buprofezin 25 SC	NS	1.25 mL/L	1.0	40
33.	Methomyl 40 SP	S	1.0 g/L	0.02	61 (one application only before flowering stage)
VIII	*Caterpillars (Helicoverpa armigera* and Spodoptera litura)**
29c.	Lambda-cyhalothrin 05 CS	NS	0.50 mL/L	0.2	30
30a.	Emamectin benzoate 05 SG	NS	0.22 g/L	0.05	25

Sr. No.	Chemical recommended for major disease & pest	Nature of chemical	Dose on formulation basis	EU MRL (mg/kg)	Pre-harvest Interval (PHI in days)
IX	Mites
25a.	Sulphur 80 WDG	NS	1.50-2.0 g/L	50.00	15
24b.	Dinocap 48 EC	NS	0.30 mL/L	0.05	50 (avoid application when tender shoots are present in canopy)
X	Plant Growth Regulators
34.	Hydrogen cyanamide 50 SL	S	30-40 mL/L	0.05	90-120
35.	Forchlorfenuron (CPPU) 0.1% L	S	1-2 ppm	0.05	22 (for 1 ppm dose) 30 (for 2 ppm dose)
36.	Gibberellic acid (GA3) Technical	S	100 ppm (Cumulative Usage)	5.00	7
37.	1-Naphthyl acetic acid 4.5% L	S	100 ppm	0.05	15
38.	Chlormequat chloride 50 SL	S	250 ppm	0.05	PHI data not available
XI	Herbicides
39.	Paraquat dichloride 24 SL	NS	5 mL/L	0.02	PHI data not available

NS = Non-systemic, S = Systemic

Note

· All the doses mentioned above are for high volume sprayers, where normal spray volume is 1000

L/ha. Spray volume can however be changed as per the efficiency of sprayers used. However, the

amount of each pesticide based on its active ingredient recommended for 1 ha area on the basis of 1000 L spray solution should be strictly maintained to minimize pesticide residues.

· Recommended PHI will be valid only if two applications of an agrochemical are given per fruiting season at the interval of 7-15 days at recommended dose except in case of Flusilazole, Methomyl and Fipronil where not more than one application per season should be given.

The PHI of the fungicide Flusilazole and insecticide Methomyl pertains to one application by foliar spray only.

· Imidacloprid (17.8 SL) application (spraying or soil drenching) should not exceed more than two times per fruiting season.

· The responsibility of usage of chemicals for the management of any of the above pests and diseases will rest with the growers in compliance with the requirements of the importers / EU and, in the minimum; all chemicals listed in Annexure 9 should be tested.

Annexure - 9
	Date: 28th January, 2013
	List of agrochemicals to be monitored for the grape season 2012-2013

Sr.	Chemicals	Harmonized
No.		EU-MRL
		(mg/kg )
I)	Organochlorine
1.	Aldrin (Aldrin and dieldrin combined expressed as dieldrin)	0.01*
2.	Chlordane (cis & trans)	0.01*
3.	Chlorothalonil	3.00
4.	DDT (all isomers, sum of p,p´-DDT, o,p´-DDT, p,p´-DDE and p,p´-TDE (DDD)	0.05*
	expressed as DDT)
5.	Dicofol (sum of p, p´ and o,p´ isomers)	0.02^
6.	Dieldrin (see Aldrin)	0.01*
7.	Endosulphan (All isomers, sum of alpha- and beta-isomers and endosulphan sulphate	0.05*
	expressed as endosulphan)
8.	Endrin	0.01*
9.	HCH (sum of isomers, except the gamma isomer)	0.01*
10.	Heptachlor (sum of heptachlor and heptachlor epoxide expressed as heptachlor)	0.01*
11.	Lindane (gamma-HCH)	0.01*
II)	Organophosphorus
12.	4-bromo-2-chlorophenol (metabolite of Profenophos)	0.01*
13.	Acephate	0.01*^
14.	Chlorfenvinphos	0.02*
15.	Chlorpyrifos	0.50
16.	Chlorpyrifos methyl	0.20
17.	Diazinon	0.01*
18.	Dichlorvos	0.01*
19.	Dimethoate (Including Omethoate)	0.02*
20.	Edifenphos	0.01*
21.	Ethion	0.01*
22.	Etrimfos	0.01*
23.	Fenitrothion	0.01*
24.	Fenthion (fenthion and its oxygen analogue, their sulfoxides and sulfone expressed as	0.01*
	parent)
25.	Glufosinate-ammonium (sum of glufosinate, its salts, MPP and NAG expressed as	0.10*
	glufosinate equivalents)
26.	Glyphosate	0.50
27.	Iprobenphos	0.01*
28.	Malathion (sum of malathion and malaoxon expressed as malathion)	0.02*
29.	Methamidophos	0.01*
30.	Monocrotophos	0.01*
31.	Omethoate (refer to Dimethoate)	0.02*
32.	Oxydemeton- methyl (sum of oxydemeton methyl and demeton-S-methylsulfone	0.01*
	expressed as oxydemeton methyl)
33.	Parathion ethyl	0.05*
	1

Sr.	Chemicals	Harmonized
No.		EU-MRL
		(mg/kg )
34.	Parathion methyl (sum of Parathion methyl and paraoxon methyl expressed as Parathion	0.01*^
	methyl)
35.	Phenthoate	0.01*
36.	Phorate (sum of phorate, its oxygen analogue and their sulfones expressed as phorate)	0.01*^
37.	Phosalone	0.01*^
38.	Phosphamidon	0.01*
39.	Pirimiphos-methyl	0.05*
40.	Profenophos	0.01*^
41.	Propetamphos	0.01*
42.	Quinalphos	0.05*
43.	Temephos	0.01*
44.	Thiometon	0.01*
45.	Triazophos	0.01*

III)	Synthetic Pyrethroids
46.	Allethrin and Bioallethrin	0.01*
47.	Bifenthrin	0.20
48.	Cyfluthrin (including other mixtures of constituent isomers sum of isomers)	0.30
49.	Cypermethrin (including other mixtures of constituent isomers sum of isomers)	0.50
50.	Deltamethrin	0.20
51.	Ethofenprox (Etofenprox)	5.00
52.	Fenpropathrin	0.01*
53.	Fenvalerate & Esfenvalerate (sum of RR & SS isomers)	0.10
54.	Fenvalerate & Esfenvalerate (sum of RS & SR isomers)	0.02*
55.	Lambda-cyhalothrin	0.20
56.	Permethrin (sum of isomers)	0.05*
57.	tau- Fluvalinate	0.10
58.	Transfluthrin	0.01*

IV)	Triazines
59.	Atrazine	0.05*
60.	Flufenzine	0.02^
61.	Simazine	0.20

V)	Acylamino acid fungicides
62.	Benalaxyl including other mixtures of constituent isomers including Benalaxyl-M (sum	0.30
	of isomers)
63.	Metalaxyl & Metalaxyl-M	2.00
64.	Oxycarboxin	0.01*^
65.	Propanil	0.10*

VI)	Carbamates
66.	Bendiocarb	0.01
67.	Benfuracarb	0.02*^
68.	Benomyl (see carbendazim)	0.30
69.	Carbaryl	0.01*^
70.	Carbofuran (sum of Carbofuran and 3-hydroxy-carbofuran expressed as Carbofuran)	0.01*^
71.	Carbosulfan	0.01*^
	2

Sr.	Chemicals	Harmonized
No.		EU-MRL
		(mg/kg )
72.	Dazomet (Methylisothiocyanate resulting from the use of Dazomet and metam)	0.02*
73.	Fenobucarb	0.01*
74.	Indoxacarb (sum of R and S isomers)	2.00
75.	Iprovalicarb	2.00
76.	Methomyl and Thiodicarb (sum of methomyl and thiodicarb expressed as methomyl)	0.02*
77.	Propoxur	0.05*
78.	Thiobencarb (Benthiocarb)	0.10*
79.	Thiodicarb (see Methomyl)	0.02*

	VII)		Pyrimidines
80.			Fenarimol	0.30
	VIII)		Triazoles
81.			Cyazofamid	0.50
82.			Bitertanol	0.05*
83.			Difenoconazole	0.50
84.			Flusilazole	0.05
85.			Hexaconazole	0.01^
86.			Myclobutanil	1.00
87.			Paclobutrazol	0.05
88.			Penconazole	0.20
89.			Propiconazole	0.30
90.			Tebuconazole	2.00
91.			Tetraconazole	0.50
92.			Triadimefon (sum of triadimefon and triadimenol)	2.00
	IX)		Imidazole
93.			Fenamidone	0.50
94.			Iprodione	10.00
	X)		Oxazole
95.			Famoxadone	2.00
	XI)		Phthalimide
96.			Captafol	0.02*
97.			Captan	0.02*
	XII)		Benzimidazole
98.			Carbendazim (including Benomyl)	0.30
99.			Thiophanate-methyl	0.10*
	XIII)		Dithiocarbamates
100.			Dithiocarbamates (Mancozeb, Maneb, Propineb, Metiram, Thiram, Zineb and Ziram	5.00
			collectively estimated as CS2)
	XIV)		Nicotinoids
101.			Acetamiprid	0.20
102.			Clothianidin (see thiamethoxam)	0.60
	103.		Dinotefuran		0.01*
	104.		Flonicamid (sum of flonicamid, TNFG and TNFA) (R)		0.05*
105.			Imidacloprid	1.00
106.			Thiacloprid	0.02*
		3

Sr.	Chemicals	Harmonized
No.		EU-MRL
		(mg/kg )
107.	Thiamethoxam (sum of thiamethoxam and clothianidin expressed as thiamethoxam)	0.50

XV)	Dinitrophenol
108.	Dinocap (sum of dinocap isomers and their corresponding phenols expressed as dinocap)	0.05*
	and Meptyldinocap
XVI)	Aliphatic Nitrogen fungicides
109.	Cymoxanil	0.20
XVII)	Morpholine
110.	Dimethomorph	3.00
111.	Tridemorph	0.01*^
XVIII)	Substituted Thiourea
112.	Diafenthiuron	0.01*
113.	Diuron (Diuron including all components containing 3,4- dichloroaniline moiety	0.05*
	expressed as 3,4-dichloroaniline)
114.	Iodosulfuron-methyl (iodosulfuron-methyl including salts, expressed as iodosulfuron-	0.02*
	methyl)
115.	Isoproturon	0.05*
116.	Linuron	0.05*
117.	Lufenuron	1.00
118.	Pencycuron	0.05*
XIX)	Benzoylphenyl urea
119.	Flufenoxuron	1.00
XX)	Strobilurin
120.	Azoxystrobin	2.00
121.	Kresoxim methyl	1.00
122.	Pyraclostrobin	1.00
123.	Trifloxystrobin	5.00
XXI)	Phenyl pyrazole
124.	Fipronil (sum of fipronil + sulfone metabolite (MB46136) expressed as fipronil)	0.005*
125.	Chlorantraniliprole	1.00
XXII)	Pyrazole
126.	Fenpyroximate	0.30
XXIII)	Nitrophenyl ether
127.	Oxyfluorfen	0.10
XXIV)	Dinitroaniline
128.	Pendimethalin	0.05*
129.	Trifluralin	0.01*^
XXV)	Anilide/acetanilide and chloroacetanilide
130.	Alachlor	0.01*^
131.	Butachlor	0.01*
132.	Carboxin	0.05*
133.	Flufenacet (sum of all compounds containing the N fluorophenyl-N-isopropyl moiety	0.05*
	expressed as flufenacet equivalent)
134.	Metolachlor (with S-Metolachlor)	0.05*
135.	Novaluron	0.01*
	4

Sr.	Chemicals	Harmonized
No.		EU-MRL
		(mg/kg )

XXVI)	Miscellaneous group of chemicals
136.	1-Naphthylacetic acid (alphanapthyl acetic acid)	0.05*
137.	2,4-D (sum of 2,4-D and its esters expressed as 2,4-D)	0.05*
138.	6-Benzyl adenine	0.01*
139.	Abamectin (sum of avermectin B1a, avermectinB1b and delta-8,9 isomer of avermectin	0.01*
	B1a)
140.	Azadirachtin	1.00
141.	Bifenazate	0.01*
142.	Buprofezin	1.00
143.	Cartap hydrochloride	0.01*
144.	Chlorfenapyr	0.01*^
145.	Chlormequat (CCC)	0.05*
146.	Diflubenzuron	1.00
147.	Homobrassinolide	0.01*†
148.	Diquat	0.05*
149.	Dithianon	3.00
150.	Dodine	0.20*
151.	Emamectin Benzoate	0.05
152.	Ethephon	0.70
153.	Fenazaquin	0.20
154.	Flubendiamide	2.00
155.	Forchlorfenuron (CPPU)	0.05*
156.	Fosetyl-Al (sum fosetyl + phosphorous acid and their salts, expressed as fosetyl)	100.00
157.	Gibberellic acid	5.00
158.	Hexythiazox	1.00
159.	Hydrogen cyanamide (Cyanamide including salts expressed as cyanamide)	0.05*
160.	Isoprothiolane	0.01*
161.	Mandipropamid	2.00
162.	Mepiquat	0.30
163.	Metribuzin	0.10*
164.	Milbemectin (sum of MA4+8,9Z-MA4, expressed as milbemectin)	0.05*
165.	Oxadiazon	0.05*
166.	Paraquat	0.02*
167.	Propargite	7.00
168.	Pyriproxyfen	0.05*
169.	Spinosad (sum of Spinosyn A+D)	0.50
170.	Spiromesifen	0.02*
171.	Trichlorfon	0.01*^
172.	Tricyclazole	0.05*
173.	Uracil	1.00†

XXVII)	Inorganic
174.	Cadmium	0.05#
175.	Copper compounds (all copper fungicides as elemental Cu; Bordeaux Mixture, Copper	50.0
	oxychloride, Copper hydroxide)
176.	Lead	0.20#
	5

Sr.	Chemicals	Harmonized
No.		EU-MRL
		(mg/kg )
177.	Sulphur	50.0

* EU-MRL set at LOQ (mg/kg) as perhttp://ec.europa.eu/sanco_pesticides/public/index.cfm?event=substance.selection

† These are natural products. EU-MRL does not exist for these chemicals. Hence, their MRL is set at the LOQ of the method developed and validated at the National Referral Laboratory of the NRC for Grapes.

#Reference: Commission Regulation (EC) No 1881/2006 of 19th December 2006.

^ COMMISSION REGULATION (EU) No 899/2012 of 21st September 2012.

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Whatever i know

Sunday 10 November 2013

MRL List for grapes season 2013-14

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